1 accumulator cell exists question The accumulator cell is in the automobile key electric
appliance part, its performance directly affects the automobile the
start. The present automobile starts uses the starting motor to
start the way without one exception. In the start process
specially is in the start instantaneous, because the starting motor
rotational speed is zero, does not have the induced electric
potential, therefore the starting current is: 1=E/Rm+Rs+Rl Among: E is the accumulator cell idling
terminal voltage, RM is the starting motor armature resistance, RB is
the accumulator cell 内阻, RL is the line resistance. Because RM, RB, RL extremely low, the starting current is
extremely big. For example with 12V, the 45Ah accumulator cell
starts installs 1.9 litres diesel engines instantaneous the
automobiles, the accumulator cell voltage falls in the start from
12.6V to approximately 3.6V! Start process accumulator cell
voltage waveform like chart 1; The start instant electric
current reaches 550A, approximately for accumulator cell 12C discharge
ratio! Start process accumulator cell current waveform like
chart 2, (electric current sensor electric current/voltage
transformation ratio: 100A/V). Although the vehicle with
the accumulator cell is the start special-purpose accumulator cell,
may the high percentage electric discharge, but may see in chart 1,
time 10 time of above high percentage electric discharge accumulator
cell performance changes very much badly, moreover, the so high
percentage electric discharge to the accumulator cell damage also is
extremely obvious. The start process voltage fierce change also
is the greatly strengthened electronmagetic interference, may create
the electrical equipment "to fall the electricity", forces the
electrical equipment to start the process after the generator to
finish on again electricity, computer in this process extremely easy
dying machine. Therefore, regardless of or improves the
automobile from the improvement automobile electrical equipment
electromagnetic environment the start performance and the accumulator
cell performance, lengthens the service life to consider, improves the
automobile power source in the start process performance is necessary.


The question solution may enlarge the accumulator cell
the capacity, but needs to increase very many, causes the volume to
increase, this certainly is not the good solution. Are parallel
the super capacitor and the accumulator cell may solve this problem
well. 2 super capacitors principles and characteristic 2.1 super capacitors principles The super capacitor is one kind of electric capacity may
reach several thousand farads the electric capacity enormous
capacitors. According to the capacitor principle, the electric
capacity is decided to the electrode between is away from and the
electrode surface area, in order to obtain the so great electric
capacity, the super capacitor reduces between as far as possible the
electrode the distance, the increase electrode surface area. Has
used 双电?the principle and the activated charcoal porous
electrode for this, super capacitor structure like chart 3.
双电?the medium exerts voltage when the capacitor two
electrodes, in approaches the electrode on the dielectric medium
contact surface to produce with the electrode carries the electric
charge opposite electric charge and is fettered on the medium contact
surface, forms in fact capacitor two electrodes, like chart 4, very
obvious, two electrodes distances are extremely small, only several
nanometer, simultaneously the activated charcoal porous electrode may
obtain the enormous electrode surface area, may amount to the 200m2/
gram. Thus this kind of structure super capacitor has the
enormous electric capacity and may save the very big static
electricity energy. Speaking of the stored energy, super
capacitor this characteristic is situated between traditional between
the capacitor and the battery. When between two pole plates the electric potential is lower
than the electrolyte the oxidation reduction electrode potential, on
the electrolyte contact surface the electric charge cannot be
separated from the electrolyte, the super capacitor for the normal
work condition (usually is below 3V), when the capacitor beginnings
and ends voltage surpasses the electrolyte the oxidation reduction
electrode potential, the electrolyte will decompose, will be the
abnormal condition. Because along with super conductive
discharge, on negative plate electric charge by external circuit
泄放, on electrolyte contact surface electric charge response
reduction. From this may see: The super capacitor
sufficient electric discharge process throughout is the physical
process, does not have the chemical reaction. Therefore the
performance is stable, with using the chemical reaction accumulator
cell is different.

2.2 main characteristics Although the super capacitor energy density is the
accumulator cell 5% perhaps are less, but this energy storage way may
apply in the traditional accumulator cell deficiency and the
short-time high-peak current. Compares the battery to say that,
this kind of super capacitor has following several superiority: The electric capacity big, the super capacitor uses the active
carbon powder and the activated charcoal textile fiber takes the
polarizable electrode, with electrolyte contact area big increase,
according to electric capacity formula, two pole plates surface areas
bigger, then the electric capacity is bigger. Therefore, the
common 双电?capacity of condenser is very easy to surpass 1F, its
appearance caused the cable telegram vessel the capacity scope
suddenly to jump 3 ~ 4 magnitudes, at present the monomer super
capacitor maximum electric capacity may reach 5000F. Sufficient electric discharge life very long, may reach 500,000
times, or 90,000 hours, but the accumulator cell sufficient electric
discharge life is very difficult to surpass 1,000 time; May
provide the very high discharging current, if the 2700F super
capacitor fixed discharging current is not lower than 950A, the
electric discharge peak value electric current may reach 1680A, the
common accumulator cell usually cannot have the so high discharging
current, some high discharging currents accumulator cells the service
life which will flow off in the so high electric discharge electricity
greatly reduce. May dozens of seconds to several minute in rapid charge rates,
but the accumulator cell will fill the electricity in the so short
time will be extremely dangerous perhaps is nearly impossible. May in the very wide temperature range the normal work (-40 ?
~ +70 ?, but the accumulator cell very difficultly especially maybe
under the low temperature environment works in the high temperature;
The super capacitor uses the material is the security and
non-toxic, but the lead-acid battery, the nickel cadmium accumulator
cell has the toxicity; Moreover, the super capacitor may
wilfully parallel use increases the electric capacity, after if adopts
presses the measure, but also may connect the use. 3 super capacitors and the accumulator cell combinations
improvement automobile starts the performance 3.1 electricity performance improvement


Uses the super capacitor and the accumulator cell is
parallel when starts the process voltage waveform like chart 5,
current waveform like chart 6. With chart 1, chart 2 compares
the start instantaneous voltage to drop from only uses when the
accumulator cell 3.2V promotes 7.2V; The starting current
enhances from 560A to 1200A; The start instant power source
output enhances from 2kW to 8.7kW; The start process steady
voltage enhances 9.4V from 7V; The start process steady electric
current enhances 440A from 280A; The start process power source
steady output enhances from 2.44kW to 4.12kW. 3.2 starts performance improvement The super capacitor and the accumulator cell parallel
application may enhance the locomotive the start performance, the
super electric capacity (450F/16.2V) with 12V, the 45Ah accumulator
cell parallel start installs 1.9 litres diesel engines the
automobiles, in 10 Celsius degree-hour of steady starts, although in
this kind of situation, when does not connect the super capacitor, the
accumulator cell also may start, but uses the super capacitor and the
accumulator cell parallel time starting motor speed and the
performance extremely is all good. As a result of the power
source output enhancement, the start speed by only uses when the
accumulator cell start speed 300rpm, increases 450rpm;
Especially in enhances the automobile in the cold season
starting performance (higher starting moment) on, the super capacitor
is extremely significant, in below zero 20 Celsius degree-hour,
because the accumulator cell performance greatly drops, is very
possible not to be able normally to start or must to start many times
can be successful, when the super capacitor and the accumulator cell
are parallel then only needs a time of ignition. Its merit is
extremely obvious. 3.3 pair of accumulator cells applications condition
improvement When the super capacitor and the accumulator cell are
parallel, because the super capacitor equivalent series resistance
(ESR) far is lower than the accumulator cell 内阻, therefore,
electric current provides in start instantaneous 1200A in the starting
current 800A by the super capacitor, the accumulator cell only
provides 400A the electric current. Obviously is lower than only
uses the accumulator cell 560A, effectively reduced the battery plate
polarization, prevented the accumulator cell 内阻 rise enable the
start process the steady voltage to obtain the enhancement. Most
main is the battery plate polarization reduces not only is
advantageous to lengthens the accumulator cell the service life,
moreover also may eliminate the frequent start to the accumulator cell
life influence. |