> Abstract: A nanotechnology can apply from
the automobile body to the wheel, nearly has covered the automobile
complete. A nanotechnology on the automobile widespread
application, will reduce the automobile various parts to wear, reduces
the automobile consumption, will reduce the automobilism cost;
In certain degree, but also can eliminate the automobile exhaust
pollution, the improvement discharges, will be the core technology
which the automobile develops, this article mainly elaborated a
nanotechnology in aspect the and so on revertex, baking varnish and
exhaust application. When the integrated circuit replaces the electron tube and
the semiconductor transistor initial period, in 1959 American Nobel
prize winner Charlie 费曼 (Richard Phillips Feynman), predicted at
the American physics annual meeting which the US California Institute
of Technology convened that, "If the people can come up the
processing material in the atomic/member criterion, the manufacture
installment, will be able some many exciting recent discovery, the
people will be able to open a brand-new world." Today, 费曼
this prediction sixth branch after starts to realize, this is the
present is all the rage global a nanotechnology. The so-called nanotechnology, is refers in 0.1 - 100
nanometer scopes, the research electron, atomic and the molecular
inherent laws and the characteristic, and use in to make each kind of
material a brand-new comprehensive science and technology.
Among: 1 nanometer was equal to 1/1 billion meter, the
such small space, is in fact the constituent archery target
fundamental unit, atomic and the molecular space. When the
material quilt "the smashing" is tiny to a nanometer level and makes
"a nanometer material", not only the light, the electricity, the heat,
the magnetism changes, moreover has the radiation, the absorption, the
adsorption and so on many new characteristics. Has invented the
electronic scanning tunnel microscope since the beginning of the 80's,
the world was born to nanometer to make the unit a microcosm research
discipline - nanometer science, entered for the 90's, a nanometer
science obtained the rapid development, has produced a nanometer
material study, a nanometer chemical industry study, nanometer
mechanics, nanometer biology and so on, from this the nanotechnology
product which produced also emerges one after another incessantly, and
started to involve the automobile profession. A nanotechnology
is the core technology which the automobile develops. A
nanotechnology can apply from the automobile body to the wheel, nearly
has covered the automobile complete. A nanotechnology on the
automobile widespread application, will reduce the automobile various
parts to wear, reduces the automobile consumption, will reduce the
automobilism cost; In certain degree, but also can eliminate the
automobile exhaust pollution, the improvement discharges. Now
many automobiles product started to use a nanotechnology, small
nanometer will cause the automobile to have the enormous change. First, the vehicle will make the application plastic
quantity with the plastic rubber automobile more and more to be many.
A nanometer plastic may change the traditional plastic the
characteristic, presents the outstanding physical performance:
Intensity high, thermal stability strong, the proportion is
smaller. Because the nanometer granule size is smaller than the
visible light wave length, a nanometer plastic may demonstrate the
good transparency and a higher glossiness, such nanometer plastic will
have the widespread use on the automobile. After the
nanotechnology processing partial materials resistance to wear is the
brass 27 time, steel and iron 7 times. The automobile uses the
rubber to be biggest by the tire amount used. In in the tire
rubber production, the rubber helps medicinal preparation majority of
Cheng Fenti the shape, like the carbon black, the white carbon black
and so on make up the strong auxiliaries, the promoter, the
antioxidant and so on. Says by the powder body shape matter,
nanometer is the present stage main development tendency. In
fact, a nanometer material and the rubber industry originally relate
namely is quite close, the majority of rubber powder help the
medicinal preparation particle size all or approach the nanometer
material scope in the nanometer material scope, for example carbon
black particle size approximately 11 ~ 500nm; White carbon black
particle size in 11 ~ 110nm. Uses a nanometer material in the
rubber product production, used the carbon black from at the beginning
of 20th century to make up strongly started, the 40's developed the
successful nanometer white carbon black to make up the strong rubber
manufacture tire. At present in the world the famous tire
factory gradually uses the white carbon black to replace the carbon
black manufacture green tire and the energy conservation tire, has
substituted for 5% ~ 10% carbon black according to the investigation.
The new generation of nanotechnology has succeeded utilizes
other nanometer granules achievement to help the medicinal
preparation, but no longer limits in the use carbon black or the white
carbon black, like ZnO, CaCO3, Al2CO3, TiO2 and so on, the biggest
change is, the tire color no longer only is restricted in the black,
but can have diverse the bright color. Moreover regardless of in
performance and so on intensity, resistance to wear or anti- aging,
the new nanometer tire compares the traditional tire to come
outstanding, for example the tire side rubber anti- fissure
performance from 100,000 time will enhance to 500,000. In
addition, the American general automobile and the Mongte North America
company has at present succeeded the development to new goods come
into the market a generation of nanometer plastic material, called it
the polyolefine thermosplastic elastomer, it is one kind of high
performance polyolefine product, becomes the rubber elasticity under
the normal temperature, has the density slightly, curving big, the low
temperature anti- impact performance high, is easy to process, may to
duplicate uses and so on the characteristic. The polyolefine
thermosplastic elastomer the application most greatly potential market
is substitutes for the polyvinyl-chloride in the vehicle to apply to
the large-scale fitting, compares with the polyvinyl-chloride, besides
may recycle, but also has bears the ultraviolet ray, the luster for a
long time stably, the quality is lighter and so on the merit.
The correlation industry forecast, in the future 20 years, the
nanometer level compound material fitting massively will substitute
for the existing vehicle with the plastic product, will have the
suitable market potential. This product is quite widespread in
automobile fitting application domain. Outside the automobile in
the support, mainly uses in the bumper bar, the radiator, the chassis,
the automobile body 外板, the wheel 护罩, the sliding roof and
other protection block glues, keeps out the wind the block glue and so
on. In the assorted items, mainly uses in the display board and
in plays the part of the board, the security aerocyst material and so
on. Chart 2, a carbon nanometer tube will serve as the rotor the
nanometer motor picture () the automobile application plastic quantity
more and more to be slightly many. The nanometer material not
only strengthens the function in plastic application, moreover also
can change the traditional plastic the characteristic, for example,
nanometer granule size small, the diaphaneity is good, joins in the
plastic to cause the plastic to change very much compactly, causes the
plastic to present the outstanding physical performance: The
intensity high, the thermal stability strong, the proportion is
smaller. Because the nanometer granule size is smaller than the
visible light wave length, a nanometer plastic may demonstrate the
good transparency and a higher glossiness. In addition, the
traditional plastic anti- aging energy balance, affects its promoted
use. This is because in the sunlight ultraviolet ray wave length
between 200 ~ 400nm, this wave band is easy to cause the high polymer
the molecular chain break, thus causes the material to get older, but
so long as increases in the plastic material can absorb the
ultraviolet ray a nanometer granule, namely can solve this problem,
like SiO2, TiO2 and so on. Every this all sorts, obviously
nanometer plastic on automobile application widespread. Second, the vehicle with baking varnish coating automobile
baking varnish flaking and the aging, is creates the automobile
artistic degree to change the difference the primary factor, take gets
older as the variable which is thorny also controls with difficulty.
The influence baking varnish gets older factor very many, but
most essential when is in the sunlight the ultraviolet ray, is similar
to a section to state, the ultraviolet ray is easy to cause the
material the molecular chain break, then causes the material
performance to get older, the high polymer plastic like is, the
organic coating also like is. More detailed said, because the
ultraviolet ray can cause in the coating mainly to become the membrane
matter the molecular chain break, forms extremely in a lively way
游离? these 游离?further cause entire mainly becomes the
membrane matter member chain the decomposition, finally causes the
coating aging deterioration. Speaking of the organic coating,
because the ultraviolet ray is in all factors, most has corrosive,
therefore if can avoid the ultraviolet ray the function, then may
largely enhance the baking varnish to bear the aged performance.
At present most can effectively camouflage the ultraviolet ray
the material, the head pushes a TiO2 nanometer granule. A TiO2
nanometer granule is one of at the end of 1980s development main
nanometer materials. The nanometer TiO2 optics effect changes
along with the particle size, nanometer rutile TiO2 has in particular
along with the angle changes color the effect, is in the automobile
baking varnish is most important and most has the development future
to change the nature material. Nanometer TiO2 scatters to the
ultraviolet ray shield primarily, the particle size affects one of
scattering power important attributes. Obtains by the theory
inferential reasoning, the nanometer TiO2 particle size between 65 ~
130nm, it is best to the ultraviolet ray scattering effect. But
uses a nanometer paint, prevented when collision slightly scratches
the appearance, automobile manufacturer 戴姆?- Chrysler
Corporation announced on the other day, year's end uses one kind of
automobile body spurts spreads with the new nanometer paint from 2003,
prevented when collision slightly scratches appearance. This
company scientific researcher passes through this kind of nanometer
paint which more than 4 years researches and develops, may in spurt
spreads after on the automobile body to form a compact network
structure, during includes many small ceramic pellets. Through
the experiment which carries on to 150 automobiles indicated, this
kind of nanometer paint not only the radiance outdoes 40% compared to
the traditional paint, moreover when automobile body with other object
slight collisions, it prevented scratches the performance which
appears also to have the traditional paint to be much better than.
The fresh paint in will run quickly to the near future E, S and
SLK and so in many series passenger vehicle uses, and will start from
2004 on this company other all series passenger vehicle to use this
kind of new nanometer paint. Third, the vehicle with the exhaust catalyst material
along with developing nation economy and so on the China continues
largely to grow, the global automobile holds the quantity also year by
year to climb, but grows the automobile exhaust contamination concern
is day by day serious, has become the important topic which the
various countries' government pays attention. Installs the
catalyst switch, is at present solves the automobile exhaust pollution
fundamental mode. Uses in the catalyst which the automobile
exhaust purifies to have many kinds, but the mainstream is by the
precious metal platinum, the arrowhead used in ancient times, the
rhodium took three Yuan catalyst, it discharges in the waste gas to
the automobile CO, HC, NOx has the very high catalyst transformation
efficiency. But the precious metal has: (1) the resources
scarce, obtains is not easy, the price is expensive; (2) is easy
to have Pb, S, P is poisoned, but causes characteristic and so on
catalyst expiration. Therefore in under the maintenance good
transformation effect premise, are partial or completely substitutes
for the precious metal, seeks other high performance catalyst
materials to become the inevitable tendency. Substitutes for the
precious metal take the nanometer level rare earth material to do as
the catalyst, is one of present development tendencies.
Rare-earth element function unique, atomic structure special
activeness is high, nearly may have the function with all elements,
thus has the unique catalysis and the nature. Joins in the
precious metal catalyst it to be possible largely to enhance the
precious metal catalyst the toxin immunity to be able, the high
temperature stability, simultaneously may reduce the precious metal
amount used, therefore the rare-earth element may say is the quite
ideal automobile exhaust catalyst or it helps the medicinal
preparation. Moreover, after because the material makes a
nanometer pellet to have the surface and light-sized and so on the
effect causes the material performance to have the sudden change, thus
has other more outstanding performance, therefore makes the rare earth
material a nanometer granule, will apply has the effect to the
automobile catalyst switch which other materials will be unable to
compare. At present our country already developed one kind with
the nanotechnology manufacture emulsifier, joined the gasoline after
the certain proportion, might cause to look like a Sangtana kind of
passenger vehicle to reduce 10% about the oil consumption. Makes
one pay attention, the nanotechnology application on the fuel cell,
may save the massive costs. Because a nanometer material has
outstanding under the room temperature condition stores the hydrogen
ability, according to tests the result, under the room temperature
atmospheric pressure, approximately 2/3 hydrogen prefers by to be able
to release from these nanometer materials, may not need the expensive
ultralow temperature liquid hydrogen to store up the installment.
Wuhan University chemistry and the molecular academy of science
has obtained the breakthrough in the nanometer level titanium dioxide
research aspect. Uses the Wuhan University patent technology
production nanometer level titanium dioxide, its cost only has the
overseas cost 1/about 4. Nanometer level titanium dioxide being
published is on the century 80's later period a titanium dioxide
research area new progress. The date, the US scientist
discovered this matter may widely apply to the high-quality passenger
vehicle 金属?面漆 and so on the aspect. Japan already
establishes the spreading nanometer level titanium dioxide in the
highway two sides and the tunnel the photochemical catalysis board
除氮 oxide compound to guard against the automobile exhaust.
At present, in the world only has the minority several companies
to be able to produce the nanometer level titanium dioxide. The synthesis above may know, future the automobile
technology development, will have enormous to dispense the
nanotechnology close correlation, certainly, if will be able
automobile all spots all nanometer, its attachment value inevitably
greatly to increase, but relative will say, its cost and the selling
price also largely will enhance. Therefore, until now, true
nanometer also 商业?the auto parts very were still limited.
But without a doubt, the automobile industry is the modern
industry important symbol, a nanotechnology will apply to the future
automobile technology development will be a inevitable trend, also
surely will be able to become the guarantee which the automobile
technology will promote. Believes in the near future, a
nanotechnology will certainly in the automobile manufacture domain to
obtain a more widespread application. Reference: L. Chico,
V. H. Crespi, L. X. Benedict, M. L. Cohen, and S. G. Louie, Phys. Rev.
Lett. 76 (1,996) 971 "Mixing Nanotube Structures to Make a Tiny
Switch," R. F. Service, Science 271 (1,996) 1232. |