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In galvanization waste water processing uses REMOVE MT and the conventional method contrasts the experiment
Origin: Input time: 07-04-26 13:56:02English version

>Introduces: REMOVE MT can in the normal temperature and the waste water each kind of metallic ion for example: Hg2+, Cd2+, Cu2+, Pb2+, Mn2+, Ni2+, Zn2+, Cr3+, Fe2+ and so on the rapid response, the production water insoluble stings the compound salt, and forms the cotton wool shape to precipitate, thus achieved removes the heavy metal ion the goal. Has the flocculation body thickly, precipitates quickly, dehydrates quickly, the post-processing is easy, the sludge quantity are few, does not have characteristic and so on second pollution, but widely applies to the galvanization industry, the electronics industry, the petrified industry, the metal working industry, trash burns down processing, a power plant smoke gas washes and so on the profession contains heavy metal ion waste water processing. This experimental goal mainly is for compare REMOVE MT and the conventional method removes the heavy metal ion the effect.
Essential character:Galvanization waste water floc test heavy metal

1. Experimental content

Use NaOH using REMOVE MT and the convention to carry on the processing galvanization waste water contrast experiment, the experimental water sample for the scene random sampling, separately obtains after the experiment best joins the quantity and the processing step, and comparison test result content.

2. Original water water quality situation

Obtains the original water water quality target after the examination as follows: (Unit: Mg/L)

Total Fe2+Ni2+Cu2+Zn2+PHTotal nitrogen
140.1215.6220.9330.41.75

In the original water the total metallic ion content is: 207.07 mg/L.

3. Experimental plan

3.1 experiments the instrument

PH meter, ORP meter, electrically operated mixer, 1500ml beaker

3.2 medicament preparations

(1) 10% density caustic soda solution

(2) 5% diluted concentration REMOVE MT

(3) 10% sulfuric acid solution

(4) 0.1% gathers the third thin amide solution

4. Testing sequence

4.1 uses REMOVE MT

(1) takes waste water 1L;

(2) joins about 10% sodium hydroxide 11.5 ml, adjusts PH to 6.5 about;

(3) joins 5% REMOVE MT (diluted concentration is 5%) 2.5 ml stirs responds 5 min;

(4) joins 0.1% to gather third thin amide 0.3 ml fast to stir 0.5 min, the idling speed stirs 1 min;

(5) settles 3 min, is accepted after passing an examination the serum to filter, in examination processing water heavy metal ion residual density.

Note:When experimental definite REMOVE MT removes the heavy metal ionic reaction end point, the ORP electric potential reduces to 60 millivolts (from + 180 millivolts to 120 millivolts).

4.2 uses NaOH

(1) takes waste water 1L;

(2) joins about 10% sodium hydroxide 16.78 ml, adjusts PH to 10.0 about;

(3) under PH=9.5, stirs responds 10 min;

(4) joins 0.1% to gather third thin amide 1.0 ml fast to stir 0.5 min, the idling speed stirs 1 min;

(5) settles 3 min, on the serum filters, joins 10% sulfuric acid solution 3.75ml, adjusts PH to 7.5;

(6) examination after NaOH processing in water heavy metal ion residual density.

5.test results

In 5.1 processing water heavy metal ion concentration contrast

Unit: Mg/L

Total Fe2+Ni2+Cu2+Zn2+PH
Uses REMOVE MT0.02090.01850.0020.00647.5
Uses NaOH0.350.260.40.1627.5 (by PH9.5 opposing argument)

5.2 adds the dose contrast

Unit: Ml

10NaOHjoins the quantity5REMOVE MTjoins the quantity10H2SO4joins the quantity0.1gathers the third thin amideto join the quantity
Uses REMOVE MT11.52.5---0.3
Uses NaOH16.78---3.751.0

5.3 working costs analyze

The market at present the medicament expense is detailed as follows:

H2SO4 98% 650 Yuan/tons

NaOH 2,300 Yuan/tons

REMOVE MT 15,000 Yuan/tons

Gathers the third thin amide 12,000 Yuan/tons

Two methods medicament expenses respectively be (process 1 ton waste water):

Uses NaOH:

1.678×2.3 + 0.375×0.65 + 0.001×12

= 4.12 Yuan/ton processing water

Uses REMOVE MT:

1.15×2.3 + 0.125×15.0 + 0.0003×12

= 4.52 Yuan/ton processing water

6. Generalized analysis

Uses REMOVE the MT processing waste water, although the medicament expense has the enhancement, but has the following merit:

(1) reaction time may reduce 1/2 about the time, the processing water is limpid, the water leakage directly is the PH neutrality;

(2) reduces PH to return mediates the principle working procedure;

(3) settling reduces about 1/3, also settling structure loose, is easy to filter, is not easy to stop up the mesh, may lengthen cleans up filter press the cycle, simultaneously saves the sludge processing expense.

(4) through the ORP way, is easy to realize the treating processes automatic control;

(5) filters out in the thing the heavy metal ion not instead to dissolve (under general acidic condition);

(6) for processed the water sales commission to create the condition.

The generalized analysis uses REMOVE the MT processing waste water, the processing expense should be compares the conventional alkalizing processing way to have reduces. The processing water completely satisfies the national standard to discharge the request.

(1)author introduces: Male, Zhejiang Jiashan person, presently unit of work: Jiasha County earth sewage treatment project limited company, Zhejiang, 314,100. Tel:13067581282

Chief-editor: Article author:

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